Publications

New(74) “Semireduction of Alkynes Using Formic Acid with Reusable Pd-Catalysts”

Iwasaki, R.; Tanaka, E.; Ichihashi, T.; Idemoto, Y.; Endo, K.*

J. Org. Chem. 2018, 83, 13574–13579.


 

(73) “Development of Neighboring Electrophilic Activation of Active Center in Catalytic Reactions via Organometallic Intermediates”

Endo, K.*

Bull. Chem. Soc. Jpn. 2017, 90, 649–661.


(72) “Silver-Catalyzed Allylation of Ketones and Intramolecular Cyclization via Carbene Intermediates from Cyclopropenes Under Ambient Conditions”

Nakano, T.; Endo, K.*; Ukaji, Y.

Chem. Asian J. 2016, 11, 713–721.

72

(71) “(Z)-Selective Enol Triflation of a-Alkoxyacetoaldehydes: Application to Synthesis of (Z)-Allylic Alcohols via Cross-Coupling Reaction and [1,2]-Wittig Rearrangement”

Kurosawa, F.; Nakano, T.; Soeta, T.; Endo, K.; Ukaji, Y.*

J. Org. Chem. 2015, 80, 5696–5703.

71

(70) “Copper(I)-Catalyzed Carbometalation of Nonfunctionalized Cyclopropenes Using Organozinc and Grignard Reagents”

Nakano, T.; Endo, K.*; Ukaji, Y.

Synlett 201526, 671–675. 

 

70

(69) “Regioselective Introduction of Substituents to the meso-Position of Pyrromethenone Derivative – Application to the Synthesis of Sterically Fixed Phytochrome Chromophore Anchored to the C15 meso-Position”

Tanaka, Y.; Iwamoto, R.; Sakata, R.; Soeta, T.; Endo, K.; Fujinami, S.; Inomata, K.; Ukaji, Y.*

Heterocycles 2014, in press.

69

 

(68) “One-Pot Cross-Coupling of Diborylmethane for the Synthesis of Dithienylmethane Derivatives”

Endo, K.*; Ishioka, T.; Shibata, T.*

Synlett 201425, 2184–2188.

highlighted by Synfacts 2014, 1265.

GA 

 

(67) “Highly Chemo-, Enantio-, and Regioselective Synthesis of α,α-Disubstituted Furanones via Cu-Catalyzed Conjugate Addition”

Endo, K.*; Yakeishi, S.; Takayama, R.; Shibata, T.*

Chem. Eur. J. 201420, 8893–8897.

highlighted by Synfacts 2014, 1043.

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(66) “Catalytic Tandem C–C Bond Formation/Cleavage of Cyclopropene for Allylzincation of Aldehydes or Aldimine Using Organozinc Reagents”

Nakano, T.;  Endo, K.*; Ukaji, Y.

Org. Lett. 2014, 16, 1418–1421.

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(65) “Stereoselective Synthesis of (2Z,4E)-2,4-pentadien-1-ols via Sequential 1,4-Elimination Reaction and [1,2]-Wittig Rearrangement Starting from (E)-4-Alkoxy-2-butenyl Benzoates”

Nakano, T.; Soeta, T.; Endo, K.; Inomata, K.; Ukaji, Y.*

J. Org. Chem. 201378, 12654–12661.

65
 

(64) “Silver(I) Oxide-Promoted Cross-Coupling Reaction of (Diborylmethyl)trimethylsilane”

Endo, K.*; Kurosawa, F.; Ukaji, Y.

Chem. Lett. 201342, 13631365.

64

 

(63) “Chemoselective Carbozincation of Cyclopropene for C–C Bond Formation and Cleavage in Single Operation”

Endo, K.*; Nakano, T.; Fujinami, S.; Ukaji, Y.

Eur. J. Org. Chem. 2013, 65146518.

 63

 

(62) “Magnesium-Tartramide Complex Mediated Asymmetric Strecker-Type Reaction of Nitrones Using Cyanohydrin”

Sakai, T.; Soeta, T.; Endo, K.; Fujinami, S.; Ukaji, Y.*

Org. Lett. 201315, 2422–2425.

 62

 

(61) “BINAM-mono-PHOS as New Entry for Multinuclear Cu-Catalysts in Asymmetric Conjugate Addition of Organozinc Reagents”

Endo, K.*; Takayama, R.; Shibata, T.*

Synlett 201324, 1155–1159.

highlighted by Synfacts 2013, 959.

61

 

(60) “Functionalized BINOL-mono-PHOS for Multinuclear Cu-Catalysts in Asymmetric Conjugate Addition of Organozinc Reagents”

Endo, K.*; Yakeishi, S.; Hamada, D.; Shibata, T.*

Chem. Lett. 201342, 547–549.

60

 

(59) “Effect of Multinuclear Cu/Al-Complexes in Highly Asymmetric Conjugate Addition of Trimethylaluminum to Acyclic Enones”

Endo, K.*; Hamada, D.; Yakeishi, S.; Shibata, T.*

Angew. Chem. Int. Ed. 201352, 606–610.

highlighted by Synfacts 2013, 299.

59

 

(58) “Facile Synthesis of Cyclic Polyphenylenes by Consecutive Inter- and Intramolecular Cycloadditions of ortho-meta-, and para-Phenylene-Tethered Triynes”

Shibata, T.*; Fujimoto, M.; Hirashima, H.; Chiba, T.; Endo, K.

Synthesis 201244, 3269–3284.

58

 

(57) “Cationic iridium-catalyzed enantioselective activation of secondary sp3 C–H bond adjacent to nitrogen atom”

Pan, S.; Matsuo, Y.; Endo, K.; Shibata, T.*

Tetrahedron 201268, 9009–9015.

57

 

(56) “One-Pot Synthesis of Symmetrical and Unsymmetrical Diarylmethanes via Diborylmethane”

Endo, K.*; Ishioka, T.; Ohkubo, T.; Shibata, T.*

J. Org. Chem. 201277, 7223–7231.

Featured Article.

56

 

(55) “Cross Coupling between sp3-Carbon and sp3-Carbon Using a Diborylmethane Derivative at Room Temperature”

Endo, K.*; Ohkubo, T.; Ishioka, T.; Shibata, T.*

J. Org. Chem. 201277, 4826–4831.

55

 

(54) “Multinuclear Cu-Catalysts Based on SPINOL-PHOS in Asymmetric Conjugate Addition of Organozinc Reagents”

Endo, K.*; Hamada, D.; Yakeishi, S.; Ogawa, M.; Shibata, T.*

Org. Lett. 201214, 2342–2345.

highlighted by Synfacts 2012, 878.

54

 

(53) “Detour and Direct Induction of Methyl-Containing Chiral Centers via Catalytic C–H or C–C Bond Formation”

Kohei Endo*, Takanori Shibata*

Synthesis 201244, 1427–1452.

53

 

(52) “Ru-catalyzed β-selective and enantioselective addition of amines to styrenes initiated by direct arene-exchange”

Otsuka, M.; Yokoyama, H.; Endo, K.; Shibata, T.*

Org. Biomol. Chem. 201210, 3815–3818.

highlighted by Synfacts 2012, 881.

52

 

(51) “Enantioselective synthesis of tripodal cyclophanes and pyridinophanes by intramolecular [2+2+2] cycloaddition”

Shibata, T.*; Miyoshi, M.; Uchiyama, T.; Endo, K.; Miura, N.; Monde, K.

Tetrahedron 201268, 2679–2686.

highlighted by Synfacts 2012, 494.

51

 

(50) “Ir(I)-Catalyzed Intermolecular Regio- and Enantioselective Hydroamination of Alkenes with Heteroaromatic Amines”

Pan, S.; Endo, K.; Shibata, T.*

Org. Lett. 201214, 780–783.

50

 

(49) “Asymmetric ortho-lithiation of 1,n-dioxa[n]paracyclophane derivatives for the generation of planar chirality”

Kanda, K.; Hamanaka, R.; Endo, K.; Shibata, T.*

Tetrahedron 201268, 1407–1416.

49

 

(48) “Highly enantioselective synthesis of silahelicenes using Ir-catalyzed [2+2+2] cycloaddition”

Shibata, T.*; Uchiyama, T.; Yoshinami, Y.; Takayasu, S.; Tsuchikama, K.; Endo, K.

Chem. Commun. 201248, 1311–1313. 48

 

(47) “Stereoselective Synthesis of Allylsilanes Bearing Tetrasubstituted Olefin via 2,2-Diborylethylsilane”

Endo, K.*; Sakamoto, A.; Ohkubo, T.; Shibata, T.*

Chem. Lett. 201140, 1440–1442.

47

 

(46) “Cationic Ir(I)-Catalyzed sp3 C-H Bond Alkenylation of Ureas with Alkynes for the Synthesis of 2,3-Disubstituted Indoles”

Shibata, T.*; Hirashima, H.; Kasagawa, M.; Tsuchikama, K.; Endo, K.

Synlett 2011, 2171–2176.

 46

 

(45) “Ir(I)-Catalyzed Enantioselective Secondary sp3 C-H Bond Activation of 2-(Alkylamino)pyridines with Alkenes”

Pan, S.; Endo, K.; Shibata, T.*

Org. Lett. 201113, 4692–4695.

45

 

(44) “Ir(III)-Catalyzed Room-Temperature Synthesis of Multisubstituted Benzofurans Initiatedby C-H Activation of α-Aryloxy Ketones”

Shibata, T.*; Hashimoto, Y.; Otsuka, M.; Tsuchikama, K.; Endo, K.

Synlett 2011, 2075–2079.

44

 

(43) “Regioselective Addition of Various Heteronucleophiles to (Styrene)Cr(CO)3 Complexes”

Otsuka, M.; Endo, K.; Shibata, T.*

Organometallics 201130, 3683–3685.

43

 

(42) “Chemoselective Suzuki Coupling of Diborylmethane for Facile Syntesis of Benzylboronates”

Endo, K.*; Ohkubo, T.; Shibata, T.*

Org. Lett. 201113, 3368–3371.

highlighted by Synfacts 2011, 1000.

42

 

(41) “Chiral Rh- and Ir-catalyzed intramolecular cycloaddition of hexaynes for the construction of new chiral skeletons”

Shibata, T.*; Chiba, T.; Hirashima, H.; Ueno, Y.; Endo, K.

Heteroatom. Chem. 201122, 363–370.

41

 

(40) “Multinuclear Pd/Zn Complex-Catalyzed Asymmetric Alkylative Ring-Opening Reaction of Oxabicyclic Alkenes”

Endo, K.*; Tanaka, K.; Ogawa, M.; Shibata, T.*

OrgLett201113, 868–871.

40

 

(39) “Enantioselective construction of new chiral cyclic scaffolds using [2 + 2 + 2] cycloaddition”

Shibata, T.*; Uchiyama, T.; Hirashima, H.; Endo, K.

Pure ApplChem201183, 597–605.

39

 

(38) “Facile Catalytic SNAr Reaction of Nonactivated Fluoroarenes with Amines Using h6-Benzene Ru(II) Complex”

Otsuka, M.; Yokoyama, H.; Endo, K.; Shibata, T.*

Synlett 201017, 2601–2606.

38

 

(37) “Chemoselective and Regiospecific Suzuki Coupling on a Multisubstituted sp3-Carbon in 1,1-Diborylalkanes at Room Temperature”

Endo, K.*; Ohkubo, T.; Hirokami, M.; Shibata, T.*

JAmChemSoc2010132, 11033–11035.

37

 

(36) “Stereoselective Synthesis of Tetrasubstituted Alkenylboronates via 1,1-Organodiboronates”

Endo, K.*; Hirokami, M.; Shibata, T.*

JOrgChem201075, 3469–3472.

highlighted by Synfacts 2010, 852.

36

 

(35) “Enantioselective Intermolecular [2+2+2] Cycloaddition of Dienynes for the Construction of Adjacent Three Chiral Centers”

Shibata, T.*; Otomo, M; Endo, K.

Synlett 2010, 1235–1238.

35

 

(34) “Enantioselective Synthesis of Planar-Chiral [1,n]-dioxa[n]paracyclophanes via Catalytic Asymmetric Ortho-Lithiation”

Kanda, K.; Endo, K.; Shibata, T.*

OrgLett201012, 1980–1983.

highlighted by  Synfacts 2010, 777.

34

 

(33) “Multinuclear Catalyst for Copper-Catalyzed Asymmetric Conjugate Addition of Organozinc Reagents”

Endo, K.*; Ogawa, M.; Shibata, T.*

AngewChemIntEd201049, 2410–2413.

highlighted by Synfacts2010, 679.

33

 

(32) “Sequential Catalytic Reactions for the Synthesis of Benzofulvenes Using an Iridium Complex with Dual Function”

Tsuchikama, K.; Kasagawa, M.; Endo, K.; Shibata, T.*

Synlett 2010, 97–100.

highlighted by Synfacts 2010, 294.

32

 

(31) “Catalytic SNAr reaction of non-activated fluoroarenes with amines via Ru-η6-arene complexes”

Otsuka, M.; Endo, K.; Shibata, T.*

ChemCommun201046, 336–338.

31

 

(30) “Iridium-Catalyzed Selective Synthesis of 4-Substituted Benzofurans and Indoles via Directed Cyclodehydration”

Tsuchikama, K.; Hashimoto, Y.; Endo, K.; Shibata, T.*

Adv. Synth. Catal. 200917, 2850–2854.

highlighted by Synfacts 2010, 153.

30

 

(29) “The First Catalytic Enantioselective Synthesis of Chiral Tetraphenylenes by Consecutive Inter- and Intramolecular Cycloadditions of Two Triynes”

Shibata, T.*; Chiba, T.; Hirashima, H.; Ueno, Y.; Endo, K.

AngewChemIntEd200948, 8066–8069; Selected as VIP.

Highlighted by Angew. Chem. Int. Ed. 201049, 672–674.

29

 

(28) “Enantioselective Synthesis of Chiral Tripodal Cage Compounds by [2+2+2] Cycloaddition of Branched Triynes”

Shibata, T.*; Uchiyama, T.; Endo, K.

OrgLett200911, 3906–3908.

highlighted by Synfacts 2009, 1364.

28

 

(27) “Synthesis of Ethyl 2-Ethanoyl-2-methyl-3-phenylbut- 3-enoate”

Fujimoto, T.; Endo, K.; Nakamura, M.; Nakamura, E.*

OrgSynth200986, 325–332.

27

 

(26) “Synthesis of 1,1-Organodiboronates via RhICl-Catalyzed Sequential Hydroboration of 1-Alkynes”

Endo, K.*; Hirokami, M.; Shibata, T.*

Synlett 2009, 1331–1335.

26

 

(25) “Indium-Catalyzed [1 + n] Annulation Reaction between β-Ketoester and α,ω-Diyne”

Tsuji, H.*; Tanaka, I.; Endo, K.; Yamagata, K.-i.; Nakamura, M.; Nakamura, E.*

OrgLett200911, 1845–1847.

25

 

(24) “Cationic Ir(I)-Catalyzed sp3 C–H Bond Alkenylation of Amides with Alkynes”

Tsuchikama, K.; Kasagawa, M.; Endo, K.; Shibata, T.*

OrgLett200911, 1824–1826.

highlighted by Synfacts 2009, 782.

24

 

(23) “The first Sonogashira Coupling for the enantioselective generation of planar chirality in cyclophanes”

Kanda, K.; Koike, T.; Endo, K.; Shibata, T.*

ChemCommun2009, 1870–1872.

23

 

(22) “Efficient Formation of Ring Structures Utilizing Multisite Activation by Indium Catalysis”

Ito, Y.; Yamagata, K.-i.; Tsuji, H.; Endo, K.; Nakamura, M.; Nakamura, E.*

JAmChemSoc2008130, 17161–17167.

22

 

(21) “DMAP-Accelerated RhICl-Catalyzed Hydroboration of Vinylarenes”

Endo, K.*; Hirokami, M.; Takeuchi, K.; Shibata, T.*

Synlett 2008, 3231–3233.

21

 

(20) “Cationic iridium-BINAP complex-catalyzed addition of aryl ketones to alkynes and alkenes via directed C-H bond cleavage”

Tsuchikama, K.; Kasagawa, M.; Hashimoto, Y.; Endo, K.; Shibata, T.*

JOrganometChem2008693, 3939–3942.

20

 

(19) “Highly diastereo- and enantioselective construction of both central and axial chiralities by Rh-catalyzed [2+2+2] cycloaddition”

Shibata, T.*; Otomo, M.; Tahara, Y.; Endo, K.

OrgBiomolChem20086, 4296–4298.

19

 

(18) “Counteranion-Accelerated RhIOAc-Catalyzed Hydroboration of Vinylarenes”

Endo, K.*; Hirokami, M.; Shibata, T.*

Organometallics 200827, 5390–5393.

18

 

(17) “RhI-catalyzed Aldol-type Reaction of Organonitriles Under Mild Conditions”

Goto, A.; Endo, K.; Ukai, Y.; Irle, S.; Saito, S.*

ChemCommun2008, 2212–2214.

17

 

(16) “RhI-catalyzed Hydration of Organonitriles Under Ambient Conditions”

Goto, A.; Endo, K.; Saito, S.*

AngewChemIntEd200847, 3607–3609, chosen as a Hot Paper.

highlighted by Synfacts2008, 747.

16

 

(15) “Construction of Chiral Quaternary Carbon Center by Indium-Catalyzed Asymmetric α-Alkenylation of β-Ketoesters”

Fujimoto, T.; Endo, K.; Tsuji, H.; Nakamura, M.*; Nakamura, E.*

JAmChemSoc2008130, 4492–4496.

15

 

(14) “Stereoselective Synthesis of Trisubstituted E-Iodoalkenes by Indium-catalyzed syn-Addition of 1,3-Dicarbonyl Compounds to 1-Iodoalkynes”

Tsuji, H.; Fujimoto, T.; Endo, K.; Nakamura, M.; Nakamura, E.*

OrgLett200810, 1219–1221.

14

 

(13) “Enantioselective Syntheses of Various Chiral Multicyclic Compounds with Quaternary Carbon Stereocenters by Catalytic Intramolecular Cycloaddition”

Shibata, T.*; Tahara, Y.; Tamura, K.; Endo, K.

JAmChemSoc2008130, 3451–3457.

13

 

(12) “Iridium-Catalyzed Enantioselective Formal [4+2] Cycloaddition of Biphenylene and Alkynes for the Construction of Axial Chirality”

Shibata, T.*; Nishizawa, G.; Endo, K.

Synlett 20085, 765–768.

12

 

(11) “Carbonylative and Hydrosilylative Carbocyclization of 1,5-Diynes for the Synthesis of Cyclic Dienones”

Shibata, T.*; Nakagawa, N.; Ueno, Y.; Endo, K.

Organometallics 200827, 1342–1344.

11

 

(10) “Rh-catalyzed intermolecular and enantioselective [4+2] cycloaddition of 1,3-dienes with dimethyl acetylenedicarboxylate”

Shibata, T.*; Fujiwara, D.; Endo, K.

Org. Biomol. Chem. 20086, 464-467.

10

 

(9) “Iridium-catalyzed consecutive and enantioselective [2+2+2] cycloaddition of tetraynes and hexaynes for the construction of axially chiral biaryl system”

Shibata, T.*; Yoshida, S.; Arai, Y.; Otsuka, M.; Endo, K.

Tetrahedron 200864, 821–830.

9

 

(8) “Rhodium-catalyzed enantioselective [2+2+2] cycloaddition of diynes with unfunctionalized alkene”

Shibata, T.*; Kawachi, A.; Ogawa, M.; Kuwata, Y.; Tsuchikama, K.; Endo, K.

Tetrahedron 200763, 12853–12859.

8

 

(7) “Indium-Catalyzed Cycloisomerization of w-Alkynyl-b-ketoesters into Six- to Fifteen-Membered Rings”

Tsuji, H.; Yamagata, K.-i.; Ito, Y.; Endo, K.; Nakamura, M.; Nakamura, E.*

AngewChemIntEd200746, 8060–8062.

highlighted by Synfacts2008, 0077Synfact of the month.

 7

 

(6) “Indium-Catalyzed 2-Alkenylation of 1,3-Dicarbonyl Compounds with Unactivated Alkynes”

Endo, K.; Hatakeyama, T.; Nakamura, M.*; Nakamura, E.*

JAmChemSoc2007129, 5264–5271.

 6

 

(5) “Synthesis of Chiral α-Fluoroketones through Catalytic Enantioselective Decarboxylation”

Nakamura, M.*; Hajra, A.; Endo, K.; Nakamura, E.*

AngewChemIntEd200544, 7248–7251, selected as a VIP

5

 

(4) “A Modular Approach to α-Arylated Carbonyl Compounds via Indium Tris(bistriflylamide)-Catalyzed Regioselective Addition of β-Ketoesters to 1,3-Diynes”

Nakamura, M.*; Endo, K.; Nakamura, E.*

AdvSynthCatal. C–C bond formation Special issue, 2005347, 1681–1686.

4

 

(3) “Indium-Triflate Catalyzed Vinylation of β-Ketoesters with Acetylene Gas”

Nakamura, M.*; Endo, K.; Nakamura, E.*

OrgLett20057, 3279–3281.

 3

 

(2) “Stereoselective Synthesis of Tetra-Substituted Olefins via Addition of Zinc Enolates to Unactivated Alkynes”

Nakamura, M.*; Fujimoto, T.; Endo, K.; Nakamura, E.*

OrgLett2004, 6, 4837–4840.

2

 

(1) “Indium-Catalyzed Addition of Active Methylene Compounds to Alkynes”

Nakamura, M.*; Endo, K.; Nakamura, E.*

J. Am. Chem. Soc. 2003, 123, 13002–13003.

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